TopicalChemistry 9701PolymerisationCondensation polymerisationPaper 1

Condensation polymerisation — Paper 1 · A Level Chemistry 9701

35.1· 12 questions · 12 marks · 14 min · 2005–2025· Multiple choice

Every Cambridge A Level Chemistry Paper 1 question on condensation polymerisation, laid out as 5 A4 pages with the mark scheme below. Nothing is left out. Free to read, no account.

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Questions5 pages

Question 1: PHB (polyhydroxybutyric acid) is a natural polymer produced by a range of micro-organisms. It can also be manufactured from sugar. PHB is r…Question 2: Kevlar has the structure below. O O O O C C N N C C N N H H H H Compared to a steel rope of similar dimensions, a Kevlar rope is both light…1 / 5
Question 3: Caprolactone is a cyclic ester. It is being used increasingly for the manufacture of specialist polymers. O O caprolactone From which compo…Question 4: The diagram represents the structure of a polymer. OH OH OH OH OH OH C C C C C C H H H H H H By which method might this polymer be made? A …2 / 5
Question 5: The structure of lactic acid is shown. O H3C C CH OH OH lactic acid Which esters might form when lactic acid is heated? 1 CH3CH(OH)CO2CH(CH…Question 6: Which compounds produce three different organic products when hydrolysed? 1 2 3 O O O O O O O O O O O OQuestion 7: Which compounds produce three different organic products when hydrolysed? 1 2 3 O O O O O O O O O O O OQuestion 8: The diagram shows part of the structure of polymer X. CH3 H CH3 H CH3 H C C C C C C H CO2CH3 H CO2CH3 H CO2CH3 Which reagents react with po…3 / 5
Question 9: The repeat unit of a polymer is shown. H CN C C H CO2C2H5 n Which types of intermolecular forces exist in the solid polymer? 1 temporary di…Question 10: The diagram shows part of the structure of polymer X. CH3 H CH3 H CH3 H C C C C C C H CO2CH3 H CO2CH3 H CO2CH3 Which reagents react with po…Question 11: 5-hydroxypentanoic acid is readily converted into the cyclic compound L. L O O Which statements about this reaction are correct? 1 Acidifie…4 / 5
Question 12: A section of an addition polymer is shown. H3C CH3 C O O C H O H H H H O H C C C C C C C C H H O H O H H H H3C CH3 C C O O Which monomer is…5 / 5

Mark scheme12 answers

Answers below. Sit the paper first if you are practising.

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Chemistry 9701 · Condensation polymerisation — Paper 1

A Level · topical answer key — answer key (teacher use)

Question

Answer

Marks

1B1
2B1
3C1
4C1
5B1
6D1
7D1
8B1
9B1
10B1
11C1
12A1
1 / 1
QuestionAnswerMarksFrom
1B19701/11 Oct/Nov 2005
2B19701/11 Oct/Nov 2008
3C19701/13 May/June 2016
4C19701/13 May/June 2017
5B19701/12 Feb/March 2018
6D19701/11 Oct/Nov 2019
7D19701/13 Oct/Nov 2019
8B19701/11 Oct/Nov 2020
9B19701/12 Oct/Nov 2020
10B19701/13 Oct/Nov 2020
11C19701/13 May/June 2021
12A19701/12 Oct/Nov 2025

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Questions as text

Q1 · PHB (polyhydroxybutyric acid) is a natural polymer produced by a range of micro-organisms 9701/11 Oct/Nov 2005

30 PHB (polyhydroxybutyric acid) is a natural polymer produced by a range of micro-organisms. It can also be manufactured from sugar. PHB is readily biodegradable. CH3 O [ O CH CH2 C [ n PHB (polyhydroxybutyric acid) What type of reaction will cause PHB to break down? A addition B hydrolysis C reduction D substitution

1 marks

Answer: B

This question in 9701/11 Oct/Nov 2005

Q2 · Kevlar has the structure below 9701/11 Oct/Nov 2008

31 Kevlar has the structure below. O O O O C C N N C C N N H H H H Compared to a steel rope of similar dimensions, a Kevlar rope is both lighter and stronger. Which properties of Kevlar help to explain these facts? 1 The fibres of Kevlar align due to hydrogen bonding. 2 The mass per unit length is less in a Kevlar rope than in a steel rope. 3 The Kevlar molecule has no permanent dipole.

1 marks

Answer: B

This question in 9701/11 Oct/Nov 2008

Q3 · Caprolactone is a cyclic ester 9701/13 May/June 2016

30 Caprolactone is a cyclic ester. It is being used increasingly for the manufacture of specialist polymers. O O caprolactone From which compound could caprolactone be made by a single reaction? A OHCCH2CH2CH2CH2CHO B HOCH2CH2CH2CH2CH2CH2OH C HOCH2CH2CH2CH2CH2CO2H D HO2CCH2CH2CH2CH2CO2H Section B

1 marks

Answer: C

This question in 9701/13 May/June 2016

Q4 · The diagram represents the structure of a polymer 9701/13 May/June 2017

24 The diagram represents the structure of a polymer. OH OH OH OH OH OH C C C C C C H H H H H H By which method might this polymer be made? A polymerise ethene followed by hydration B polymerise ethene followed by oxidation with cold, acidified KMnO4 C polymerise 1,2-dichloroethene followed by hydrolysis D polymerise 1,2-dichloroethene followed by oxidation with cold, acidified KMnO4

1 marks

Answer: C

This question in 9701/13 May/June 2017

Q5 · The structure of lactic acid is shown 9701/12 Feb/March 2018

40 The structure of lactic acid is shown. O H3C C CH OH OH lactic acid Which esters might form when lactic acid is heated? 1 CH3CH(OH)CO2CH(CH3)CO2H CH3 CH O O C 2 C O O CH CH3 3 CH3CH(OH)CO2CH(OH)CH3

1 marks

Answer: B

This question in 9701/12 Feb/March 2018

Q6 · Which compounds produce three different organic products when hydrolysed? 9701/11 Oct/Nov 2019

40 Which compounds produce three different organic products when hydrolysed? 1 2 3 O O O O O O O O O O O O

1 marks

Answer: D

This question in 9701/11 Oct/Nov 2019

Q7 · Which compounds produce three different organic products when hydrolysed? 9701/13 Oct/Nov 2019

40 Which compounds produce three different organic products when hydrolysed? 1 2 3 O O O O O O O O O O O O

1 marks

Answer: D

This question in 9701/13 Oct/Nov 2019

Q8 · The diagram shows part of the structure of polymer X 9701/11 Oct/Nov 2020

40 The diagram shows part of the structure of polymer X. CH3 H CH3 H CH3 H C C C C C C H CO2CH3 H CO2CH3 H CO2CH3 Which reagents react with polymer X? 1 aqueous sulfuric acid 2 aqueous sodium hydroxide 3 sodium

1 marks

Answer: B

This question in 9701/11 Oct/Nov 2020

Q9 · The repeat unit of a polymer is shown 9701/12 Oct/Nov 2020

32 The repeat unit of a polymer is shown. H CN C C H CO2C2H5 n Which types of intermolecular forces exist in the solid polymer? 1 temporary dipole – induced dipole interactions 2 permanent dipole – permanent dipole interactions 3 hydrogen bonds

1 marks

Answer: B

This question in 9701/12 Oct/Nov 2020

Q10 · The diagram shows part of the structure of polymer X 9701/13 Oct/Nov 2020

40 The diagram shows part of the structure of polymer X. CH3 H CH3 H CH3 H C C C C C C H CO2CH3 H CO2CH3 H CO2CH3 Which reagents react with polymer X? 1 aqueous sulfuric acid 2 aqueous sodium hydroxide 3 sodium

1 marks

Answer: B

This question in 9701/13 Oct/Nov 2020

Q11 · 5-hydroxypentanoic acid is readily converted into the cyclic compound L 9701/13 May/June 2021

40 5-hydroxypentanoic acid is readily converted into the cyclic compound L. L O O Which statements about this reaction are correct? 1 Acidified sodium dichromate(VI) is used as a reagent. 2 A water molecule is produced in the reaction. 3 The reaction can be catalysed by concentrated H2SO4.

1 marks

Answer: C

This question in 9701/13 May/June 2021

Q12 · A section of an addition polymer is shown 9701/12 Oct/Nov 2025

39 A section of an addition polymer is shown. H3C CH3 C O O C H O H H H H O H C C C C C C C C H H O H O H H H H3C CH3 C C O O Which monomer is used to make this polymer? A B C D O O O O O O O O O O

1 marks

Answer: A

This question in 9701/12 Oct/Nov 2025