Cambridge A Level Chemistry 9701 — 2013 May/June Paper 5 · Variant 2

READ THESE INSTRUCTIONS FIRST Write your Centre number, candidate number and name on all the work you hand in. Write in dark blue or black pen. You may use a soft pencil for any diagrams, graphs or rough working. Do not use staples, paper clips, highlighters, glue or correction fl uid. DO NOT WRITE IN ANY BARCODES. Answer all questions. Electronic calculators may be used. You may lose marks if you do not show your working or if you do not use appropriate units. Use of a Data Booklet is unnecessary. At the end of the examination, fasten all your work securely together. The number of marks is given in brackets [ ] at the end of each question or part question. CHEMISTRY 9701/52 Paper 5 Planning, Analysis and Evaluation May/June 2013 1 hour 15 minutes Candidates answer on the Question Paper. No Additional Materials are required. UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS General Certifi cate of Education Advanced Level This document consists of 9 printed pages and 3 blank pages. [Turn over IB13 06_9701_52/3RP © UCLES 2013 *3483758140* For Examiner’s Use 1 2 Total

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3 9701/52/M/J/13 © UCLES 2013 [Turn over For Examiner’s Use 1 Calcium hydroxide, Ca(OH)2, is slightly soluble in water, approximately 1 g dm–3 at 25 °C. The molar enthalpy of solution of a solid is defi ned as the enthalpy change when one mole of the solid dissolves in water. (a) (i) Predict how the solubility of calcium hydroxide in water changes as the temperature is increased. Explain this prediction using Le Chatelier’s Principle in terms of the equilibrium between the solid calcium hydroxide and the aqueous solution, as shown in the equation below. Ca(OH)2(s) Ca2+(aq) + 2OH–(aq) ∆Hsoln = –16.7 kJ mol–1 Predict how the solubility will change as the temperature is increased. … … … Explanation … … … … (ii) Display your prediction in the form of a sketch graph between 0 °C and 100 °C. Label the axes with units and give numerical values to ensure that the line clearly shows the solubility at 25 °C. 00 [4] (b) If you were to carry out an experiment to investigate how the solubility of calcium hydroxide varies as the temperature increases name, (i) the independent variable, … (ii) the dependent variable. … [1]

4 9701/52/M/J/13 © UCLES 2013 For Examiner’s Use (c) You are to plan an experiment to determine as accurately as possible the concentration of a saturated aqueous solution of calcium hydroxide by titration with hydrochloric acid. You are reminded that the approximate solubility of calcium hydroxide is 1 g dm–3 at 25 °C. The following information gives some of the hazards associated with calcium hydroxide and hydrochloric acid. Hydrochloric acid, HCl (aq) Corrosive; Causes burns: Irritating to respiratory system. Solutions equal to or more concentrated than 6.5 mol dm–3 are corrosive. Solutions equal to or more concentrated than 2 mol dm–3 but more dilute than 6.5 mol dm–3 are said to be irritant. Calcium hydroxide, Ca(OH)2(s) Irritant; risk of serious damage to eyes. You are provided with the following materials: 250 cm3 of saturated calcium hydroxide, 50 cm3 of 2.00 mol dm–3 hydrochloric acid. Give a step-by-step description of how you would carry out the experiment by including: (i) a balanced equation for the reaction between aqueous calcium hydroxide and hydrochloric acid, (ii) a list of apparatus with volumes where appropriate, (iii) a suitable indicator with relevant colours, (iv) a calculation of the approximate concentration of a saturated aqueous solution of calcium hydroxide in mol dm–3 at 25 °C, [Ar: H, 1.0; O, 16.0; Ca, 40.1] (v) a detailed method for the dilution of the hydrochloric acid such that when a titration is carried out the two reacting volumes are approximately equal at the end-point. The relevant calculations and reasoning must be shown in full. (vi) a detailed method for carrying out suffi cient titrations to allow an accurate end-point to be obtained, (vii) an outline calculation to show how the results are to be used to determine the accurate concentration of the aqueous calcium hydroxide. [Ar: Cl, 35.5]

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6 9701/52/M/J/13 © UCLES 2013 For Examiner’s Use … … … … … … … … … … … … … … [8] (d) State one hazard that must be considered when planning the experiment and describe a precaution that should be taken to keep risks from this hazard to a minimum. You should use the information in (c). … … … … … … [2] [Total: 15]

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8 9701/52/M/J/13 © UCLES 2013 For Examiner’s Use 2 Hydrated copper(II) sulfate can be represented as CuSO4.xH2O where x is the number of molecules of H2O for each CuSO4. When the compound is heated, it loses the molecules of water leaving anhydrous copper(II) sulfate. A suggested equation is: CuSO4.xH2O(s) → CuSO4(s) + xH2O(g) An experiment is carried out to attempt to determine the value of x. ● An open crucible is weighed and the mass recorded. ● A sample of hydrated copper(II) sulfate is added to the crucible and the new mass recorded. ● The crucible with hydrated copper(II) sulfate is heated strongly for fi ve minutes and allowed to cool back to room temperature. ● The crucible with the contents is then reweighed and the mass recorded. (a) Calculate the relative formula masses, Mr, of CuSO4 and H2O. [Ar: H, 1.0; O, 16.0; S, 32.1; Cu, 63.5] [1] (b) The results of several of these experiments are recorded below. Process the results in the table to calculate both the number of moles of anhydrous copper(II) sulfate and the number of moles of water. Record these values in the additional columns of the table. You may use some or all of the columns. Masses should be recorded to two decimal places, while the numbers of moles should be recorded to three signifi cant fi gures. Label the columns you use. For each column you use include units where appropriate and an expression to show how your values are calculated. You may use the column headings A to G for these expressions (e.g. A–B). A B C D E F G mass of crucible / g mass of crucible + CuSO4.xH2O / g mass of crucible + CuSO4 / g 15.20 16.76 16.20 15.10 16.90 16.25 14.95 16.95 16.23 15.15 17.25 16.49 15.05 17.32 16.47 14.90 17.24 16.43 14.92 17.42 16.52 15.30 17.99 17.02 15.07 17.96 16.92 15.01 18.09 16.98 [2]

9 9701/52/M/J/13 © UCLES 2013 [Turn over (c) Plot a graph to show the relationship between the number of moles of anhydrous copper(II) sulfate, CuSO4 (x-axis), and the number of moles of water (y-axis). Draw the line of best fi t. It is recommended that you do not include the origin in your choice of scaling. [3]

10 9701/52/M/J/13 © UCLES 2013 For Examiner’s Use (d) Circle and label on the graph any point(s) you consider to be anomalous. For each anomalous point give a different reason why it is anomalous clearly indicating which point you are describing. … … … … … … … … [3] (e) Determine the slope of the graph. You must mark clearly on the graph any construction lines and show clearly in your calculation how the intercepts were used in the calculation of the slope. [3] (f) Comment on the reliability of the data provided in (b). … … … [1] (g) (i) Use the value of the slope of your graph calculated in (e) to suggest the correct formula for hydrated copper(II) sulfate. … … … (ii) Explain your answer to (i). … … … [2] [Total: 15]

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CAMBRIDGE INTERNATIONAL EXAMINATIONS GCE Advanced Level MARK SCHEME for the May/June 2013 series 9701 CHEMISTRY 9701/52 Paper 5 (Planning, Analysis and Evaluation), maximum raw mark 30 This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of the examination. It shows the basis on which Examiners were instructed to award marks. It does not indicate the details of the discussions that took place at an Examiners’ meeting before marking began, which would have considered the acceptability of alternative answers. Mark schemes should be read in conjunction with the question paper and the Principal Examiner Report for Teachers. Cambridge will not enter into discussions about these mark schemes. Cambridge is publishing the mark schemes for the May/June 2013 series for most IGCSE, GCE Advanced Level and Advanced Subsidiary Level components and some Ordinary Level components.

Page 2 Mark Scheme Syllabus Paper GCE A LEVEL – May/June 2013 9701 52 © Cambridge International Examinations 2013 Question Expected Answer Mark 1 (a) (i) (Solubility will) decrease Dissolving/reaction is exothermic so reaction is shifted left (owtte) Increase negates both marks. Allow: Variations in the wording but the word exothermic/heat evolved (or endothermic/heat absorbed for the reverse process) must be included. 1 1 (ii) Axes are correctly labelled AND graph is a curve/straight line showing a decrease in solubility with temperature (ignore units) Graph goes through the point 25 oC, 1 g dm–3 AND goes from 0 oC to 100 oC (Allow ecf from (i).) 1 1 (b) (i) temperature (ii) solubility (of calcium hydroxide) 1 (c) 1 2 3 4 5 6 7 8 Ca(OH)2 + 2HCl
CaCl2 + 2H2O Pipette (5, 10, 20, 25 or 50 cm3), burette (25, 50 or 100 cm3) Named indicator with colours in acid and alkaline solution. Concentration of Ca(OH)2 = 0.0135 mol dm–3 Describes making a solution of HCl in volumetric flask which must include using a burette or pipette to take a volume of HCl and making it up to the mark with water. Suggests a dilution of HCl of between 50 and 100 fold OR suggests a mixture of HCl and water that would give a dilution of between 50 and 100 fold. Titration is repeated to achieve concordant/average titre. Moles of HCl calculated from titre AND Ca(OH)2 = 0.5 x moles of HCl AND concentration of Ca(OH)2 is deduced. 1 1 1 1 1 1 1 1 (d) Calcium hydroxide OR 2.00 mol dm–3 hydrochloric acid are irritants. Eye protection must be worn. Eye protection can be goggles, glasses, face masks etc. 1 1 [Total: 15]

Page 3 Mark Scheme Syllabus Paper GCE A LEVEL – May/June 2013 9701 52 © Cambridge International Examinations 2013 2 (a) 159.6 AND 18.0 1 (b) Columns are headed with label and correct expression and units. mol of CuSO4 AND mol of H2O are correct to 3 sig figs. ECF incorrect Mr or the use of incorrect expressions into data D E F G CuSO4 C – A / g H2O B – C / g Mol CuSO4 D / 159.6 / mol Mol of H2O E / 18.0 / mol 1.00 0.56 0.00627 0.0311 1.15 0.65 0.00721 0.0361 1.28 0.72 0.00802 0.0400 1.34 0.76 0.00840 0.0422 1.42 0.85 0.00890 0.0472 1.53 0.81 0.00959 0.0450 1.60 0.90 0.0100 0.0500 1.72 0.97 0.0108 0.0539 1.85 1.04 0.0116 0.0578 1.97 1.11 0.0123 0.0617 1 1 (c) x-axis labelled ‘CuSO4 ’ and y-axis ‘H2O’ AND plotted points cover at least half the grid in both directions AND scales must be uniform including the origin if used. All 10 points plotted correctly. Best fit straight line drawn. 1 1 1 (d) Points 5 and 6 circled Point 5 (mass of crucible = 15.05) The anhydrous CuSO4 had decomposed OR prior to heating the crucible/sample was wet OR contained an impurity which decomposed/was removed on heating. Allow: some mass lost (spits) on heating Point 6 (mass of crucible = 14.90) Not all the water had been driven off the copper sulfate crystals OR anhydrous copper sulfate absorbed some water OR has an impurity that does not decompose 1 1 1

Page 4 Mark Scheme Syllabus Paper GCE A LEVEL – May/June 2013 9701 52 © Cambridge International Examinations 2013 (e) Appropriately drawn lines on the graph. Correctly read values from the graph. (Figures from the table allowed if no construction lines drawn providing graph does actually go through the points used.) Correctly calculated value of the slope given to 2 or more sig figs up to calculator value using the candidate’s figures AND with no units given. 1 1 1 (f) Most of the points are on the line OR only a few points are not on the line OR there are only a few anomalies 1 (g) (i) CuSO4.5H2O ecf on slope in (e) 1 (ii) The graph / slope is the ratio of H2O:CuSO4 is 5 / 5:1 OR the slope is the value of x 1 [Total: 15]